A substance is a matter that has a definite composition and distinct properties. It can be an element or a compound that cannot be separated into other kinds of matter by any physical process.
Homogeneous mixtures: These are mixtures that have uniform composition and properties throughout. The components are not visible to the naked eye and cannot be separated by filtration. Examples: Salt solution, sugar solution, air.
Heterogeneous mixtures: These are mixtures that do not have uniform composition. The components are visible to the naked eye and can be separated by simple physical methods. Examples: Mixture of sand and salt, mixture of oil and water, concrete.
| Property | Solution | Sol (Colloid) | Suspension |
|---|---|---|---|
| Particle Size | Less than 1 nm | 1 nm to 100 nm | More than 100 nm |
| Visibility | Particles not visible | Particles not visible with naked eye | Particles visible with naked eye |
| Tyndall Effect | Does not show | Shows | Shows |
| Stability | Stable | Stable | Unstable |
| Separation | Cannot be separated by filtration | Cannot be separated by filtration | Can be separated by filtration |
| Examples | Sugar solution, salt solution | Milk, blood, ink | Muddy water, chalk in water |
Pure substances: (a) Ice, (c) Iron, (d) Hydrochloric acid, (e) Calcium oxide, (f) Mercury
Not pure substances: (b) Milk, (g) Brick, (h) Wood, (i) Air (these are mixtures)
Solutions: (b) Sea water, (c) Air, (e) Soda water
Not solutions: (a) Soil, (d) Coal
Will show Tyndall effect: (b) Milk, (d) Starch solution
Will not show Tyndall effect: (a) Salt solution, (c) Copper sulphate solution
Elements: (a) Sodium, (d) Silver, (f) Tin, (g) Silicon
Compounds: (e) Calcium carbonate, (k) Methane, (l) Carbon dioxide
Mixtures: (b) Soil, (c) Sugar solution, (h) Coal, (i) Air, (j) Soap, (m) Blood
Chemical changes: (a) Growth of a plant, (b) Rusting of iron, (d) Cooking of food, (e) Digestion of food, (g) Burning of a candle
Physical changes: (c) Mixing of iron filings and sand, (f) Freezing of water
Steps for making tea:
Mass of solute (sodium chloride) = 36 g
Mass of solvent (water) = 100 g
Mass of solution = Mass of solute + Mass of solvent = 36 g + 100 g = 136 g
Concentration = (Mass of solute / Mass of solution) × 100
Concentration = (36 / 136) × 100 = 26.47%
Therefore, the concentration of the saturated solution is 26.47%.
(a) What mass of potassium nitrate would be needed to produce a saturated solution of potassium nitrate in 50 grams of water at 313 K?
From the table, at 313 K, 62 g of potassium nitrate dissolves in 100 g of water to form a saturated solution.
For 50 g of water, mass of potassium nitrate needed = (62/100) × 50 = 31 g
(b) Pragya makes a saturated solution of potassium chloride in water at 353 K and leaves the solution to cool at room temperature. What would she observe as the solution cools? Explain.
As the solution cools, she would observe crystals of potassium chloride forming and settling at the bottom. This happens because the solubility of potassium chloride decreases with decrease in temperature. At room temperature (around 293 K), the solubility is only 35 g per 100 g of water, so the excess potassium chloride crystallizes out.
(c) Find the solubility of each salt at 293 K. Which salt has the highest solubility at this temperature?
At 293 K:
Ammonium chloride has the highest solubility (37 g/100g water) at 293 K.
(d) What is the effect of change of temperature on the solubility of a salt?
The solubility of most salts increases with increase in temperature. However, the extent of increase varies for different salts. For example, potassium nitrate shows a large increase in solubility with temperature, while sodium chloride shows only a small increase.
(a) Saturated solution: A solution in which no more solute can be dissolved at a given temperature is called a saturated solution. Example: When sugar stops dissolving in water and settles at the bottom, the solution is saturated.
(b) Pure substance: A substance that has a fixed composition and distinct properties. It contains only one type of particles. Examples: Elements like gold, copper; compounds like water, sodium chloride.
(c) Colloid: A heterogeneous mixture where the particle size is between 1 nm to 100 nm. The particles are not visible to naked eye but scatter light (show Tyndall effect). Examples: Milk, blood, fog.
(d) Suspension: A heterogeneous mixture where the particle size is more than 100 nm. The particles are visible to naked eye, settle down on standing, and can be separated by filtration. Examples: Muddy water, chalk in water.
To confirm that a colourless liquid is pure water: